The Chemistry of CO2 Capture in an Amine-Functionalized Metal-Organic Framework under Dry and Humid Conditions.

Investigating the Performance of Amine-Grafted Silica-Base Adsorbents in CO2 Removal from a Natural Gas Stream Using a Diffusion Based Mathematical Model

Abstract:  In this study adiffusion based mathematical model was developed to compare the performance of amine-grafted adsorbents with that of 13X zeolite in a fixed-bed adsorption tower which is used to capture CO2 from both humid and dry nitrogen stream under industrial conditions. The results show that the performance of amine-grafted adsorbent and 13X zeolite is almost the same in the dry ...

Carbon Dioxide Capture on Metal-organic Frameworks with Amide-decorated Pores

CO2 is the main greenhouse gas emitted from the combustion of fossil fuels and is considered a threat in the context of global warming. Carbon capture and storage (CCS) schemes embody a group of technologies for the capture of CO2 from power plants, followed by compression, transport, and permanent storage. Key advances in recent years include the further development of ne...

Efficient removal of cobalt(II) ion from aqueous solution using amide-functionalized metal-organic framework

In this study, an amide-functionalized metal-organic framework, namely TMU-24 was selected to adsorb Co(II) from wastewater with an adsorption capacity of 500 mg. g-1 in less than 20 minutes in neutral pH (pH=7). The effect of diverse parameters such as adsorbent dosage, competitive ions, and contact time on the adsorption process was investigated to find the optimal amounts of them. Also, the ...

An amine/imine functionalized microporous MOF as a new fluorescent probe exhibiting selective sensing of Fe3+ and Al3+ over mixed metal ions

Nowadays metal-organic frameworks with multiple luminescent centers are very fascinating as multifunctional luminescent material because of their luminescence properties, which could be systematically tuned by deliberate use of organic ligands and metal ions. In this research, we explored a microporous mixed-ligand MOF for highly selective and sensitive detection of metal ions. A two-fold inter...

In this paper, the effect of nanocatalytic metal-organic framework based on copper metal and bis-tetrazolamine (CuBTA) ligand functionalized with cobalt (II) oxide nanoparticles on the thermal decomposition behavior of ammonium perchlorate (AP), using differential survey calorimetry (DSC) has been reviewed. First, the metal-organic framework (CuBTA) was synthesized from the raw materials of cop...